INVESTIGADORES
HUMANA Rita Mariangeles
artículos
Título:
Modeling and experimental validation of the discharge of lithium-sulfur batteries with nanoporous carbons following the Quasi-Solid-State Mechanism
Autor/es:
D. LEVITAN ; P.M. MUÑOZ ; C.A. CALDERÓN ; G. CORREA; R. HUMANA; E.P.M. LEIVA
Revista:
ELECTROCHIMICA ACTA
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Año: 2023 vol. 466
ISSN:
0013-4686
Resumen:
A model is proposed for the Lithium Sulfur battery within confined nanopores according to the Quasi-Solid-State reaction mechanism, and validated against an experimental discharge curve. The model reproduces quantitatively the discharge curve, showing a change of slope at 400 mAh/g, consistent with the reduction of Li2S2 into Li2S. A sensitivity analysis is performed, with transport resistivities of solid phases having the most important effect on cell capacity.
