BECAS
OVIEDO Paola Soledad
congresos y reuniones científicas
Título:
Unusual Photophysical Properties of Bimetallic and Trimetallic Cyanide-Bridged Ru(II) Polypyridines
Autor/es:
PAOLA OVIEDO; ALEJANDRO CADRANEL; JOSÉ HODAK; LUIS BARALDO
Lugar:
Massachusetts
Reunión:
Congreso; Gordon Research Conference Photochemistry; 2015
Institución organizadora:
Stonehill College Easton
Resumen:
In this work, we synthesized a series of cyanide-bridged dinuclear complexes [Ru(tpy)(bpy)(μ-CN)Ru(bpy)2(L)]2+/3+ (tpy= 2,2;6,2´-terpyridine, bpy=2,2´-bipyridine, and L =acetonitrile (-ACN), thiocyanate (-NCS-), dimethylaminopyridine (-DMAP) or water (-OH2)). When the terminal ligand is better donor group (L= NCS-), we observed longer life times.