INVESTIGADORES
DEL POPOLO Mario Gabriel
artículos
Título:
Alkylated organic cages: from porous crystals to neat liquids
Autor/es:
NICOLA GIRI ; CHRISTINE E. DAVIDSON ; GAVIN MELAUGH ; MARIO G. DEL PÓPOLO ; JAMES T. A. JONES ; TOM HASELL; ANDREW I. COOPER; PETER N. HORTON; MICHAEL B. HURSTHOUSE; STUART L. JAMES
Revista:
Chemical Science
Editorial:
Royal Society of Chemistry
Referencias:
Lugar: Londres; Año: 2012 vol. 3 p. 2153 - 2157
ISSN:
2041-580X
Resumen:
Rigid organic iminospherand cages are rendered meltable by multiple alkylation; below their melting points they can take the form of permanently porous crystals, crystals unstable to desolvation or non-porous glassy solids depending on chain length and branching; melting points as low as 50 °C are observed and a fully Newtonian liquid phase is obtained above 80 °C. Thin glassy fibres can be drawn out from a molten phase.
