INVESTIGADORES
MORZAN Uriel Nicolas
artículos
Título:
Nitrosodisulfide [S2NO]- (perthionitrite) is a true intermediate during the "cross-talk" of nitrosyl and sulfide
Autor/es:
MARCOLONGO, JUAN P.; MORZAN, URIEL N.; ZEIDA, ARI; SCHERLIS, DAMIÁN A.; OLABE, JOSÉ A.
Revista:
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Año: 2016 vol. 18 p. 30047 - 30052
ISSN:
1463-9076
Resumen:
Nitrosodisulfide S2NO- is a controversial intermediate in the reactions of S-nitrosothiols with HS- that produce NO and HNO. QM-MM molecular dynamics simulations combined with TD-DFT analysis contribute to a clear identification of S2NO- in water, acetone and acetonitrile, accounting for the UV-Vis signatures and broadening the mechanistic picture of N/S signaling in biochemistry.
