INVESTIGADORES
TAKARA Eduardo Andres
artículos
Título:
Fractional statistical theory of finite multilayer adsorption
Autor/es:
E.A. TAKARA; D.A. MATOZ-FERNANDEZ; E. QUIROGA; N.A. OCHOA; A.J. RAMIREZ-PASTOR
Revista:
APPLIED SURFACE SCIENCE
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Lugar: Amsterdam; Año: 2016 vol. 360 p. 14 - 19
ISSN:
0169-4332
Resumen:
In the present paper, finite multilayer adsorption is described as a fractional statistics problem, based onHaldane?s statistics. In this scheme, the Helmholtz free energy and its derivatives are written in terms ofa parameter g, which relates to the configuration of the molecules in the adsorbed state. For values of granging between 0 and 1 the formalism is used to model experimental data of bovine serum albumin (BSA)adsorbed onto an ion exchange resin for different values of pH and temperature. Excellent agreementbetween theory and experiments was found.
