INVESTIGADORES
ERBEN Mauricio Federico
artículos
Título:
The ionic nature of methylsulfur trichloride species
Autor/es:
RODRIGUEZ PIRANI, LUCAS SEBASTIÁN; ERBEN, MAURICIO FEDERICO; DELLA VÉDOVA, CARLOS OMAR
Revista:
INORGANIC CHEMISTRY COMMUNICATIONS
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Lugar: Amsterdam; Año: 2012 vol. 26 p. 66 - 68
ISSN:
1387-7003
Resumen:
The Raman spectrum of the methyldichloro-sulfonium(IV) chloride, CH3SCl2+Cl−, is reported. The unambiguous vibrational assignment for the CH3SCl2+ cation is made on the basis of the solid state Raman spectra aided by high-level quantum chemical calculations and a normal mode analysis. Actually, the former reported methylsulfur trichloride, CH3SCl3, can be now described as CH3SCl2+Cl−.
