INVESTIGADORES
NEUMAN Nicolas Ignacio
artículos
Título:
A mesoionic carbene complex of manganese in five oxidation states
Autor/es:
WITTWER, BENJAMIN; DICKMANN, NICOLE; BERG, STEPHAN; LEITNER, DANIEL; TESI, LORENZO; HUNGER, DAVID; GRATZL, RAFAEL; VAN SLAGEREN, JORIS; NEUMAN, NICOLÁS I; MUNZ, DOMINIK; HOHLOCH, STEPHAN
Revista:
CHEMICAL COMMUNICATIONS
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Lugar: CAMBRIDGE; Año: 2022 vol. 58 p. 6096 - 6099
ISSN:
1359-7345
Resumen:
Reaction between a carbazole-based mesoionic carbene ligand andmanganese(II) iodide results in the formation of a rare air-stablemanganese(IV) complex after aerobic workup. Cyclic voltammetryreveals the complex to be stable in five oxidation states. Theelectronic structure of all five oxidation states is elucidated chemically, spectroscopically (NMR, high-frequency EPR, UV-Vis, MCD),magnetically, and computationally (DFT, CASSCF)
