INVESTIGADORES
GIUSSI Juan Martin
artículos
Título:
Metal-organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers
Autor/es:
MATÍAS RAFTI; JUAN A. ALLEGRETTO; GUSTAVO M. SEGOVIA; JIMENA S. TUNINETTI; JUAN M. GIUSSI; ELISA BINDINI ; OMAR AZZARONI
Revista:
Materials Chemistry Frontiers
Editorial:
Royal Society of Chemistry
Referencias:
Año: 2017 vol. 1 p. 2256 - 2260
ISSN:
2052-1537
Resumen:
We used of poly-(3-sulfopropylmethacrylate) brushes as macromolecular 3D primers to promote heterogeneous nucleation and growth of archetypal ZIF-8 MOF thin films. The enhancement can be understood in terms of a high preconcentration of Zn2+ ionsin the polymer brush; that leads to a rapid increase of nucleation sites in the primer.
