INVESTIGADORES
BOUCHET Lydia Maria
artículos
Título:
Stereoselective one-pot synthesis of β-alkylsulfide enol esters. Base-triggered rearrangement under mild conditions
Autor/es:
ADRIAN A. HEREDIA; SILVIA SORIA CASTRO; LYDIA M. BOUCHET; GABRIELA OKSDATH MANSILLA; CECILIA A. BARRIONUEVO; DANIEL A. CAMINOS; FABRICIO R. BISOGNO; JUAN E. ARGÜELLO; ALICIA B. PEÑÉÑORY
Revista:
ORGANIC & BIOMOLECULAR CHEMISTRY
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Lugar: CAMBRIDGE; Año: 2014 vol. 12 p. 6516 - 6526
ISSN:
1477-0520
Resumen:
A stereoselective one-pot procedure was developed to prepare S-substituted (Z)-enol esters through abase-triggered rearrangement. This transition metal-free multicomponent approach can be performedunder an air atmosphere at room temperature, tolerates a wide set of chemical functionalities and generallyaffords high isolated yields. The (Z)-selectivity arises from the [1,4]-S- to O-acyl migration.
