INVESTIGADORES
RODRIGUEZ PIRANI Lucas Sebastian
artículos
Título:
The ionic nature of methylsulfur trichloride species
Autor/es:
LUCAS S. RODRIGUEZ PIRANI; M. F. ERBEN; C. O. DELLA VÉDOVA
Revista:
INORGANIC CHEMISTRY COMMUNICATIONS
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Lugar: Amsterdam; Año: 2012 vol. 26 p. 66 - 68
ISSN:
1387-7003
Resumen:
The Raman spectrum of the methyldichloro-sulfonium(IV) chloride is reported. The unambiguous vibrational assignment for the CH3SCl2+> cation is made on the basis of the solid state Raman spectra aided by high-level quantum chemical calculations and a normal mode analysis. Actually, the former reported methylsulfur trichloride, CH3SCl3, can be now described as CH3SCl2+Cl−
