INVESTIGADORES
HEREDIA Adrian Alberto
artículos
Título:
Stereoselective One-Pot Synthesis of Beta-Alkylsulfide Enol Esters. Base-Triggered Rearrangement Under Mild Conditions
Autor/es:
ADRIÁN A. HEREDIA; SILVIA SORIA-CASTRO; LYDIA BOUCHET; GABRIELA OKSDATH-MANSILLA; CECILIA A. BARRIONUEVO; DANIEL A. CAMINOS; FABRICIO R. BISOGNO; JUAN E. ARGÜELLO; ALICIA B. PEÑÉÑORY
Revista:
ORGANIC & BIOMOLECULAR CHEMISTRY
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Lugar: CAMBRIDGE; Año: 2014 vol. 12 p. 6516 - 6526
ISSN:
1477-0520
Resumen:
A stereoselective one-pot procedure was developed to prepare S-substituted (Z) enol esters through a base-triggered rearrangement. This transition metal-free multicomponent approach can be performed under an air atmosphere at room temperature, tolerates a wide set of chemical functionalities and generally affords high isolated yields. The (Z)-selectivity arises from the [1,4]-S- to O acyl migration.
