Dye-Sensitized TiO2 as Heterogenous Visible Light Photocatalyst for the Hydroxylation of Aryl Boronic Acids

ARGÜELLO, JUAN; HEREDIA, ADRIÁN; BOUCHET, LYDIA

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY

SOC BRASILEIRA QUIMICA

Año: 2023 p. 1 - 7

0103-5053

Herein, we report the preparation of a variety of dye-sensitized TiO2 and its application asa heterogeneous photocatalyst for the oxidative hydroxylation of boronic acids and esters tosynthesize phenols. Several organic dyes, namely eosin Y, rose bengal, purpurin, alizarin blue,fluorescein and riboflavin were combined with TiO2. The nanohybrid TiO2-eosin Y showed thebest results. Furthermore, we demonstrated a synergistic association between dyes and TiO2 thatimproves its photocatalytic properties. This methodology resulted compatible for aryl boronicacids with both electron-withdrawing and electron donor groups on the aromatic ring. Thus, thereactions were performed under heterogeneous photocatalytic conditions, employing visible light,saturated oxygen atmosphere, short reaction time, acetonitrile and water as environmentally friendlysolvents, to produce the corresponding phenols in very good to excellent isolated yields. Finally,we proposed a mechanism where the selective excitation of EY associated with TiO2 using visiblelight and the formation of the superoxide anion play a main role in this reaction.