New Route to the Synthesis of Difluorodioxirane from FC(O)OF

KARINA L. BIERBRAUER; JORGE CODNIA; MARIA L. AZCARATE; GUSTAVO A. ARGÜELLO

Inorganic Chemistry

ACS publications

Año: 2001 vol. 40 p. 2922 - 2924

Fluoroformyl hypofluorite has long been considered an unstable molecule1 because the impurities present in the products during synthesis were responsible for its decomposition. Even though FC(O)OF is well-characterized spectroscopically, its photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. though FC(O)OF is well-characterized spectroscopically, its photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. during synthesis were responsible for its decomposition. Even though FC(O)OF is well-characterized spectroscopically, its photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. though FC(O)OF is well-characterized spectroscopically, its photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. 1 because the impurities present in the products during synthesis were responsible for its decomposition. Even though FC(O)OF is well-characterized spectroscopically, its photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. though FC(O)OF is well-characterized spectroscopically, its photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. Even though FC(O)OF is well-characterized spectroscopically, its photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. its photochemical study deserves special interest. Studies on infrared multiphoton (IRMP) excitation using a pulsed CO2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. 2 laser have been undertaken in this paper. The results obtained show that the main reaction path goes through a heterogeneous reaction whose ultimate fate is the catalytic isomerization of FC(O)OF to F2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere. in the probable formation of O3 by CF2 in the stratosphere. 2CO2, a stable isomer proposed as an intermediate in the probable formation of O3 by CF2 in the stratosphere.3 by CF2 in the stratosphere. Difluorodioxirane is the only known dioxirane that may be isolated as a pure substance and that may be thermally stabilized in the gas phase at room temperature. It