INVESTIGADORES
PELLEGRINET Silvina Carla
artículos
Título:
Computational Evaluation of Asymmetric Diels-Alder Reactions of Vinylboranes with Chiral Dienes
Autor/es:
SILVINA C. PELLEGRINET; MARÍA A. SILVA; JONATHAN M. GOODMAN
Revista:
Tetrahedron Letters
Editorial:
Elsevier
Referencias:
Año: 2005 vol. 46 p. 2461 - 2464
ISSN:
0040-4039
Resumen:
The asymmetric Diels-Alder reactions of dichlorovinylborane and vinyl-9-BBN with two chiral dienes have been studied theoretically. Calculations suggest high reactivity and regio- and stereoselectivity could be achieved in these processes giving the anti para endo product. This class of reactions represents a potential stereoselective approach to a variety of chiral carbocycles.
