INVESTIGADORES
PELLEGRINET Silvina Carla
artículos
Título:
Diels-Alder Reactions of Vinylboranes: A Computational Study on the Boron Substituent Effects
Autor/es:
MARÍA. A. SILVA; SILVINA C. PELLEGRINET; JONATHAN. M. GOODMAN
Revista:
Arkivoc
Editorial:
Arkat USA
Referencias:
Año: 2003 vol. X p. 556 - 565
ISSN:
1424-6376
Resumen:
The effect of substitution on boron in the Diels-Alder reactions of vinylboranes has been investigated by a computational study performed with the B3LYP/6-31G* method. Four vinylboranes with different electronic and steric properties were chosen to study the reactivity and the regio- and stereoselectivities patterns. In general, the calculations for the reactions with cyclopentadiene, trans-piperylene and isoprene are in good agreement with experimental results.
