INVESTIGADORES
PELLEGRINET Silvina Carla
artículos
Título:
Diels-Alder Reaction of Sugar-derived Cyclic Dienophiles with Cyclopentadiene. Factors Affecting the Reactivity and Stereoselectivity
Autor/es:
SILVINA C. PELLEGRINET; ROLANDO A. SPANEVELLO
Revista:
ORGANIC LETTERS
Editorial:
American Chemical Society
Referencias:
Lugar: Washington D. C.; Año: 2000 vol. 2 p. 1073 - 1076
ISSN:
1523-7060
Resumen:
A sugar-derived cyclic dienophile showed a high exo and face selectivity in the Diels-Alder reaction with cyclopentadiene. Structural modifications on the dienophile structure were made, and the outcomes of the cycloaddition reactions were investigated. These results and the spectroscopic data recorded within a series of analogues were used to analyze the factors affecting the reactivity and exo selectivity.exo and face selectivity in the Diels-Alder reaction with cyclopentadiene. Structural modifications on the dienophile structure were made, and the outcomes of the cycloaddition reactions were investigated. These results and the spectroscopic data recorded within a series of analogues were used to analyze the factors affecting the reactivity and exo selectivity.
