INVESTIGADORES
GOMEZ German Ernesto
artículos
Título:
Insight into the Metal Content?Structure?Property Relationship in Lanthanide Metal?Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance
Autor/es:
GOMEZ, GERMÁN ERNESTO; BRUSAU, ELENA VIRGINIA; SACANELL, JOAQUÍN; SOLER-ILLIA, GALO; NARDA, GRISELDA EDITH
Revista:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Editorial:
WILEY-V C H VERLAG GMBH
Referencias:
Año: 2018 vol. 2018 p. 2452 - 2460
ISSN:
1434-1948
Resumen:
Two series of metal‐organic frameworks (MOFs) based on a flexible ligand and trivalent lanthanides were obtained hydrothermally in order to explore their optical properties at low temperatures, magnetism and catalytic activity in relation to their structural features. A multisite analysis was performed according to the 4f‐4f transitions. Moreover, the heterogeneous catalytic activity of the series was evaluated in one‐pot cyanosilylation with benzaldehyde as substrate. Recyclability, structure conservation and catalytic efficiency were also evaluated and compared with analogous compounds.
