INVESTIGADORES
SILBESTRI Gustavo Fabian
artículos
Título:
Efficient catalyst-free bi- and triaroylation of aromatic rings in a single step
Autor/es:
M.J. LO FIEGO; M. A. BADAJOZ; G.F. SILBESTRI; M.T. LOCKHART; A.B. CHOPA
Revista:
JOURNAL OF ORGANIC CHEMISTRY
Editorial:
The American Chemical Society
Referencias:
Lugar: Salt Lake City; Año: 2008 p. 9184 - 9187
ISSN:
0022-3263
Resumen:
The exceptional leaving group ability of the trimethylstannyl
group in electrophilic aromatic substitutions makes possible
the synthesis, in a single step, of bi- and triaroylarenes
through the catalyst-free, regioselective reaction of bi- and
tristannylarenes with different aroyl halides in o-dichlorobenzene
as solvent. Specific di- and triketones are obtained
in good to excellent yields (45-83%).
