INVESTIGADORES
SILBESTRI Gustavo Fabian
artículos
Título:
Two-step synthesis of di- and tristannylarenes from anilines via an SRN1 mechanism
Autor/es:
G.F. SILBESTRI; M.T. LOCKHART; A.B. CHOPA
Revista:
ARKIVOC - ONLINE JOURNAL OF ORGANIC CHEMISTRY
Editorial:
ARKAT USA INC
Referencias:
Año: 2011 vol. vii p. 210 - 220
ISSN:
1551-7004
Resumen:
The synthesis in good yields (71-85%) of di- and tristannylated benzenes from commercially available anilines, involving their conversion to the corresponding aryltrimethylammonium salts followed by the reaction with Me3SnNa 1 in liquid ammonia, is described. The results obtained clearly indicate that the stannylation reactions proceed through an SRN1 mechanism.
