INVESTIGADORES
DAMONTE Laura Cristina
artículos
Título:
Mechanochemical Reactions in Fe2O3M
Autor/es:
CUADRADO- LABORDE, CHRISTIAN; L. C. DAMONTE; L. A.MENDOZA-ZÉLIS
Revista:
HYPERFINE INTERACTIONS
Editorial:
Kluwer
Referencias:
Año: 2001 vol. 134 p. 131 - 140
ISSN:
0304-3843
Resumen:
The production of metalceramic nanodispersion by mechanical milling of powders
through the displacement reaction Fe2O3 +M → Fe + M-oxide (with M: Al, Ti) was studied. The
reaction progress with milling time was followed by recording the temperature and pressure during
the process. The samples were characterized by X-ray diffraction and Mössbauer spectroscopy at
the intermediate and final stages. In both cases self-sustained reactions were observed with different
activation times. The results confirm that mechanical work at room temperature yields the reduction
of hematite by Ti and Al. The final oxides were identified as Ti2O3 and Al2O3, respectively. The
dependence of the intermediate and final stages on the milling conditions and the starting composition
will be discussed.2O3 +M → Fe + M-oxide (with M: Al, Ti) was studied. The
reaction progress with milling time was followed by recording the temperature and pressure during
the process. The samples were characterized by X-ray diffraction and Mössbauer spectroscopy at
the intermediate and final stages. In both cases self-sustained reactions were observed with different
activation times. The results confirm that mechanical work at room temperature yields the reduction
of hematite by Ti and Al. The final oxides were identified as Ti2O3 and Al2O3, respectively. The
dependence of the intermediate and final stages on the milling conditions and the starting composition
will be discussed.2O3 and Al2O3, respectively. The
dependence of the intermediate and final stages on the milling conditions and the starting composition
will be discussed.