INVESTIGADORES
PIERELLA Liliana Beatriz
capítulos de libros
Título:
Catalysis by Microporous Materials, Proceedings of ZEOCAT "95
Autor/es:
O. ANUNZIATA; L. B. PIERELLA
Libro:
Studies in Surface Science and Catalysis
Editorial:
Elsevier
Referencias:
Lugar: Netherlands; Año: 1995; p. 574 - 581
Resumen:
Selective synthesis of 2-methyl naphthalene has been studied over HZSM-5, HZSM-11,
HSABO-11, HZBS-11, Zn-ZSM-11, Ga-ZSM-11, HY and, HZSM-20 type zeolites. The
nature of the naphthalene-methanol interaction has been investigated in order to
elucidate the reaction mechansim. According to the data obtained by FT-IR, TPD of
naphthalene, ionization potential and proton affinity of different aromatic rings, zeolites
with medium pores, and with sites of medium or high acid strengh are necessary for the
reaction. The results seem to be consistent with the Rideal type mechanism.
