INVESTIGADORES
MASSA Nestor Emilio
artículos
Título:
Evolution of Ni Local Structure in NdNiO3 Perovskite Across the Metal-InsulatorTransition
Autor/es:
C. PIAMONTEZE1, H. C. N. TOLENTINO, A.Y. RAMOS, N. E. MASSA, J. A. ALONSO, M. J. MARTINEZ-LOPE AND M. T. CASAIS
Revista:
PHYSICA SCRIPTA
Editorial:
Institute of Physics (IOP)
Referencias:
Lugar: New York; Año: 2005 vol. T115 p. 648 - 650
ISSN:
0281-1847
Resumen:
NdNiO3 presents a metal-insulator (MI) transition at 200K with decreasing temperature. This system was characterized by neutron diffraction as orthorhombic with a very symmetric Ni site and almost no modification at the NiO6 octahedra is observed across the transition.We carried out EXAFS measurements on NdNiO3 observed across the transition.We carried out EXAFS measurements on NdNiO3 observed across the transition.We carried out EXAFS measurements on NdNiO3 This system was characterized by neutron diffraction as orthorhombic with a very symmetric Ni site and almost no modification at the NiO6 octahedra is observed across the transition.We carried out EXAFS measurements on NdNiO3 observed across the transition.We carried out EXAFS measurements on NdNiO3 observed across the transition.We carried out EXAFS measurements on NdNiO3 This system was characterized by neutron diffraction as orthorhombic with a very symmetric Ni site and almost no modification at the NiO6 octahedra is observed across the transition.We carried out EXAFS measurements on NdNiO3 observed across the transition.We carried out EXAFS measurements on NdNiO3 observed across the transition.We carried out EXAFS measurements on NdNiO3 3 presents a metal-insulator (MI) transition at 200K with decreasing temperature. This system was characterized by neutron diffraction as orthorhombic with a very symmetric Ni site and almost no modification at the NiO6 octahedra is observed across the transition.We carried out EXAFS measurements on NdNiO3 observed across the transition.We carried out EXAFS measurements on NdNiO3 observed across the transition.We carried out EXAFS measurements on NdNiO3 6 octahedra is observed across the transition.We carried out EXAFS measurements on NdNiO33 from room temperature down to 10 K, crossing the MI transition and observed important local modifications at the Ni site. The phase derivative method shows that there are distorted Ni sites, with at least two different Ni-O distances, along all the temperature range measured. The modification across the MI transition concerns the increasing of the distorted phase. This hypothesis is sustained by the behavior of the Debye-Waller factor (2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. concerns the increasing of the distorted phase. This hypothesis is sustained by the behavior of the Debye-Waller factor (2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. concerns the increasing of the distorted phase. This hypothesis is sustained by the behavior of the Debye-Waller factor (2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. important local modifications at the Ni site. The phase derivative method shows that there are distorted Ni sites, with at least two different Ni-O distances, along all the temperature range measured. The modification across the MI transition concerns the increasing of the distorted phase. This hypothesis is sustained by the behavior of the Debye-Waller factor (2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. concerns the increasing of the distorted phase. This hypothesis is sustained by the behavior of the Debye-Waller factor (2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. concerns the increasing of the distorted phase. This hypothesis is sustained by the behavior of the Debye-Waller factor (2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. important local modifications at the Ni site. The phase derivative method shows that there are distorted Ni sites, with at least two different Ni-O distances, along all the temperature range measured. The modification across the MI transition concerns the increasing of the distorted phase. This hypothesis is sustained by the behavior of the Debye-Waller factor (2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. concerns the increasing of the distorted phase. This hypothesis is sustained by the behavior of the Debye-Waller factor (2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. concerns the increasing of the distorted phase. This hypothesis is sustained by the behavior of the Debye-Waller factor (2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. MI transition and observed important local modifications at the Ni site. The phase derivative method shows that there are distorted Ni sites, with at least two different Ni-O distances, along all the temperature range measured. The modification across the MI transition concerns the increasing of the distorted phase. This hypothesis is sustained by the behavior of the Debye-Waller factor (2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. concerns the increasing of the distorted phase. This hypothesis is sustained by the behavior of the Debye-Waller factor (2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. concerns the increasing of the distorted phase. This hypothesis is sustained by the behavior of the Debye-Waller factor (2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. MI transition concerns the increasing of the distorted phase. This hypothesis is sustained by the behavior of the Debye-Waller factor (2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. 2) with temperature. With decreasing temperature, when the sample is around TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition. TMI 2 rapidly increases due to the growing amount of distorted sites. These results give basis for a discussion in terms of a percolative transition.