Lithium Metal Protection by a Cross-Linked Polymer Ionic Liquid and Its Application in Lithium Battery

ANDREA CALDERÓN; ALEN VIZINTIN; JERNEJ BOBNAR; DANIEL EUGENIO BARRACO; EZEQUIEL P.M. LEIVA; A. VISINTIN

ACS Appl. Energy Mater

ACS

Año: 2020

Lithium (Li) metal has been considered as an important anode candidate to reach more powerful energy storage devices with higher gravimetric and volumetric capacities.Nevertheless, the growth of high surface area lithium (HSAL) and dendrites during the stripping / deposition of Li causes safety concern and low cycle life of Li metal batteries. Here we report the obtained results for protection of metallic lithium surface by using a gel polymer ionic liquid cross-linked by activation with UV radiation (UV-PIL). The UVPIL protects Li against a constant degradation caused by the formation of unstable lithium metal-electrolyte interphase and cell dry out due to continuous electrolyte consumption. We observed retarded growth of dendrites when lithium metal is protected with UV-PIL and due to the lower ionic conductivity of UV-PIL some differences of mass transport are present compared to carbonate based liquid electrolyte. Nevertheless, the UV-PIL@Li negative electrode was successfully applied in a Li-ion battery with lithium iron phosphate (LFP) positive electrode, showing similar behavior compared to the bare Li surface.