Connecting Metallic Nanoparticles by Optical Printing

JULIÁN GARGIULO; SANTIAGO CERROTA; EMILIANO CORTÉS; IANINA L. VIOLI; FERNANDO STEFANI

NANO LETTERS (PRINT)

AMER CHEMICAL SOC

Lugar: Washington; Año: 2016 vol. 16 p. 1224 - 1229

1530-6984

Optical printing is a simple and flexible method to bring colloidal nanoparticles from suspension to specific locations of a substrate. However, its application has been limited to the fabrication of arrays of isolated nanoparticles because, until now, it was never possible to bring nanoparticles closer together than approximately 300 nm. Here, we propose this limitation is due to thermophoretic repulsive forces generated by plasmonic heating of the NPs. We show how to overcome this obstacle and demonstrate the optical printing of connected nanoparticles with well-defined orientation. These experiments constitute a key step toward the fabrication by optical printing of functional nanostructures and microcircuits based on colloidal nanoparticles.