Electrochemical synthesis of donor-acceptor triazine based polymers with halochromic and electrochromic properties

RENFIJE, MELISA; GONZALEZ LOPEZ, EDWIN J.; MACOR, LORENA; SOLIS, CLAUDIA; DURANTINI, JAVIER; MORALES, GUSTAVO M.; OTERO, LUIS; DURANTINI, EDGARDO N.; HEREDIA, DANIEL A.; GERVALDO, MIGUEL

ELECTROCHIMICA ACTA

PERGAMON-ELSEVIER SCIENCE LTD

Lugar: Amsterdam; Año: 2024

0013-4686

Two triazine monomers substituted with aromatic α,β unsaturated ketones (chalcones) as connecting arms, holding triphenylamine or carbazole ending groups, were by the first time synthesized using commercial and inexpensive starting materials in just two steps. Triphenylamine and carbazole groups were strategically introduced in order to allow electrochemical polymerization and redox activity of the obtained films. The chalcone, together with the triphenylamine or carbazole outer groups, give rise to the formation of a donor-acceptor systems, allowing the generation of photoinduced intramolecular charge transfer (ICT) electronic transitions and providing basic sites for protonation. Because of the star-like chemical structure of the used triazine, electrochemical polymerization of these monomers conducted to the formation of hyperbranched structures. The polymeric materials exhibited not only electrochromic properties but also showed a halochromic behavior. Spectroelectrochemical studies of the films showed different colorations in the three redox states (neutral, semioxidized and fully oxidized).The color changes are fast and easily detected by the naked eye. Electrochemical parameters such as optical contrast, coloration efficiency, optical memory, and long-term stability for both films were obtained and compared.A quasi-solid window-type electrochromic device was assembled using the electrogenerated polymer with the best electrochromic performance and stability. Moreover, the triphenylamine based polymer showed reversible color changes upon acid-base vapor exposure cycles, demonstrating that this polymer can be used not only in electrochromic devices but also in acid vapor sensors.