Synthesis and Properties of an Electropolymer Obtained from a Dimeric Donor/Acceptor System with a 4,4′- Spirobi[cyclopenta[2,1‑b:3,4‑b′]dithiophene] Core

MINUDRI, DANIELA; GERVALDO, MIGUEL; OTERO, LUIS; FUNGO, FERNANDO; ORLANDI, SIMONETTA; POZZI, GIANLUCA; CAVAZZINI, MARCO

MACROMOLECULES

AMER CHEMICAL SOC

Lugar: Washington; Año: 2015 vol. 48 p. 4364 - 4372

0024-9297

The design and synthesis of two potentially electropolymerizable electron donoracceptor dyes characterized by a cruciform 4,4′-spirobi[cyclopenta[2,1-b;3,4-b?]dithiophene] core is here outlined. The new molecules feature two perpendicularly aligned cyclopentadithiophene branches, each one having an electrodimerizable, electron donor triphenylamine unit and an electron acceptor dicyanovinylene group. By merging these structural elements, the light absorption ability of the conjugated cyclopentadithiophene chromophore is extended to a broad region of the visible spectrum. The photoelectroactive film obtained from one of the dyes by electrochemical deposition technique retains the ability to generate photoinduced charge-separated states and totransport holes, turning this material into a unique example of donor-acceptor polymer with potential application in the development of organic optoelectronic devices.