On-line Copper Removal for Se Determination by Hydride Generation-Inductively Coupled Plasma Optical Emission Spectrometry

M. KAPLAN, R.A. GIL, S. CERUTTI, J.A. GÁSQUEZ, R.A. OLSINA, L.D. MARTINEZ

SPECTROSCOPY LETTERS

Taylor and Francis

Año: 2006 vol. 39 p. 593 - 603

0038-7010

Selenium determination in samples with a high copper content by hydride generation-inductively coupled plasma optical emission spectrometry (HG-ICP-OES) after on-line copper removal and selenium (VI) reduction is described. An activated carbon minicolumn was used for the retention of copper and its subsequent separation of Se. Se (VI) was then on-line reduced by heating into a PTFE coiled reactor with 12 M HCl. The analyte was introduced into a water stream containing sodium tetrahydroborate (NaBH4) in order to generate selenium hydride (H2Se)  The detection limit (DL) obtained was 0.8 µg L-1, and the precision, expressed by the relative standard deviation (RSD), was 2.5 % (n = 10; 10 µg L-1 selenium level). The present method was applied to the Se determination in two copper reference materials, MBH-39DK 3601 (with a Se content of 90 mg Kg-1) and MBH-39 DK 3604 (with a Se content of 15 mg Kg-1).