INVESTIGADORES
SALUM Maria Laura
artículos
Título:
-NMR characterization of the intermediate formed upon UV-A excitation of biopterin, neopterin and 6-hydroxymethylpterin in O2-free aqueous solutions.
Autor/es:
MARIANA VIGNONI; M. LAURA SALUM; ROSA ERRA-BALSELLS; ANDRES H. THOMAS; FRANCO M. CABRERIZO
Revista:
CHEMICAL PHYSICS LETTERS
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Año: 2009 p. 330 - 332
ISSN:
0009-2614
Resumen:
Pterins belong to a family of heterocyclic compounds present in a wide range of living systems and participate in relevant biological functions. Under anaerobic conditions, the unstable red intermediate generated by UV-A irradiation of biopterin, neopterin and 6-hydroxymethylpterin was identified by 1H NMR analysis, in alkaline D2O solutions, as 5,8-dihydro-6-formylpterin.