INVESTIGADORES
RAFTI Matias
artículos
Título:
Molecular transport properties of ZIF-8 thin films in aqueous environments: the critical role of intergrain mesoporosity as diffusional pathway
Autor/es:
MATIAS RAFTI, JIMENA TUNINETTI, ANETTE BRUNSEN, AND OMAR AZZARONI
Revista:
MICROPOROUS AND MESOPOROUS MATERIALS
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Lugar: Amsterdam; Año: 2015
ISSN:
1387-1811
Resumen:
We report here the first use of electrochemical tools to quantify molecular transport from aqueous solutions into ZIF-8 MOF thin films. Our experimental findings reveal that molecular transport through ZIF-8 films in aqueous environments is purely dominated by solvent-filled intergrain mesoporosity and exhibits two well-defined transport regimes.
