PERSONAL DE APOYO
RODRIGUEZ PRESA Maria Jose
congresos y reuniones científicas
Título:
Ion, solvent and polymer dynamics in electroactive polymer films of substituted anilines
Autor/es:
A. R. HILLMAN; M. GONSALVES; H. L. BANDEY; M. J. RODRÍGUEZ PRESA; S. RAMÍREZ; J. F. RODRÍGUEZ NIETO ; D. POSADAS
Lugar:
Los Ángeles
Reunión:
Congreso; 189th Meeting of the Electrochemical Society; 1996
Institución organizadora:
Electrochemical Society
Resumen:
Conducting polymers films based on pyrrole, tiophene and aniline have extensively studied in view of their potential-dependent electronic and optical characteristcs. For pyrrole and tiophene systems, there has been extensive exploration of substituent effects: the effects on electronic structure (manifested through doping potentials, band gap, conductivity and stability) can be dramatic. In the present study of o poly(o-aminophenol) (POAP) and poly(o-toluidine) (POT), we focus on the dynamics of heavy species, whose motions are a consequence of electron transfer. Specifically, we describe EQCM studies of ion and solvent transfers accompanying redox switching, and crystal impedance measurements that give insight into the nature of the polymer matrix within which then mobile species move.
