Mechanochemically synthesized pyrite and its electrochemical behavior as cathode for lithium batteries

PRIMO, EMILIANO N.; BRACAMONTE, MARÍA V.; LUQUE, GUILLERMINA L.; BERCOFF, PAULA G.; LEIVA, EZEQUIEL P. M.; BARRACO, DANIEL E.

JOURNAL OF SOLID STATE ELECTROCHEMISTRY (PRINT)

SPRINGER

Año: 2019 vol. 23 p. 1929 - 1938

1432-8488

This study presents a simple and scalable synthesis of pyrite (FeS2) starting from S and Fe powders, which involves high-energyball milling of precursor powders followed by a thermal treatment. The formation of the desired product was confirmed by X-raydiffraction, Raman spectroscopy, thermogravimetric analysis, and X-ray photoelectron spectroscopy. After the synthesis, spherical FeS2 nanoparticles of ~ 85 nm in size were obtained, with a highly crystalline face-centered cubic structure and no secondaryphases. The synthesized material was tested as cathode material for lithium batteries. The cathodes delivered good electrochemical lithium storage properties, such as a reversible capacity as high as 470 mAh g−1 even after 120 cycles and a good ratecapability. Furthermore, aspects regarding the reaction mechanism and common electrochemical features of Li/FeS2 batteries arediscussed.