INVESTIGADORES
STRUMIA Miriam Cristina
artículos
Título:
- Thionine immobilized in crosslinked chitosan films
Autor/es:
LEANDRO GERBINO; MIRIAM STRUMIA; RODRIGO IGLESIAS; ANA BARUZZI
Revista:
SENSORS AND ACTUATORS B-CHEMICAL
Editorial:
ELSEVIER SCIENCE SA
Referencias:
Año: 2008 p. 455 - 461
ISSN:
0925-4005
Resumen:
Redox and acidbase properties of thionine immobilized in crosslinked chitosan films are analyzed. The experimental conditions for the
preparation of the films are described. Results obtained with cyclic voltammetry, spectroelectrochemistry and spectrophotometry indicate that
the immobilized dye retains the redox and acidbase activity of free thionine. An acid dissociation constant (Ka) for the immobilized dye ofKa) for the immobilized dye of
Ka = 2.7×10−11 was obtained.
Due to the stable and reversible pH dependent optical signal of the studied film, this membrane can be used as a building component of an optical
pH sensor.
Due to the stable and reversible pH dependent optical signal of the studied film, this membrane can be used as a building component of an optical
pH sensor.
a = 2.7×10−11 was obtained.
Due to the stable and reversible pH dependent optical signal of the studied film, this membrane can be used as a building component of an optical
pH sensor.