Multilayer adsorption with multisite- occupancy

ROMÁ F.; RAMIREZ PASTOR A. J.; RICCARDO J. L.

Kyongju

Conferencia; Proceedings of the second Pacific Basin Conference on Adsorption Science and Technology; 2003

Yonsei University- Korea

A closed- form analytic solution for the thermodynamics of multilayer adsorption of linear species on one and two- dimensional surfaces is presented. The theoretical description is obtained by using a new formalism, which provides the isotherm of multilayer adsorption isotherm at monolayer. The validity of the approach is tested by comparison with Monte Carlo simulations.