Coagels from Ascorbic Acid Derivatives

SANTIAGO DANIEL PALMA; HILARIO MANZO, RUBEN; ALBERTO ALLEMANDI, DANIEL; LAURA FRATONI,; LO NOSTRO, PIERANDREA

Langmuir

Año: 2002 vol. 18 p. 9219 - 9224

0743-7463

The 6-O-ascorbic acid alkanoates, ascorbyl-OCO(CH2)n-2CH3 (ASCn), behave as anionic surfactants in water. At low water content (10% w/v) aqueous dispersions also form coagels at room temperature. These hydrated crystalline phases transform to micellar solutions or gel phases, depending on the length of the hydrophobic chain in the surfactant. The formation and properties of these phases were studied through surface tension, differential scanning calorimetry (DSC), X-ray diffraction (XRD), conductivity, and environmental scanning electron microscopy (ESEM). On heating, the shorter ascorbyl alkanoates (n eO-ascorbic acid alkanoates, ascorbyl-OCO(CH2)n-2CH3 (ASCn), behave as anionic surfactants in water. At low water content (10% w/v) aqueous dispersions also form coagels at room temperature. These hydrated crystalline phases transform to micellar solutions or gel phases, depending on the length of the hydrophobic chain in the surfactant. The formation and properties of these phases were studied through surface tension, differential scanning calorimetry (DSC), X-ray diffraction (XRD), conductivity, and environmental scanning electron microscopy (ESEM). On heating, the shorter ascorbyl alkanoates (n en e 10) exhibit a coagel to micelle phase transition. By contrast the longer homologues (ng11) exhibit a coagel to gel transition. The temperature, ¢H, and ¢S of the transitions depend on the length of the aliphatic side chain. The different phase behavior is related to the interplay of the competing molecular interactions that involve the hydrophobic chains of the amphiphiles, their headgroups, and the solvent.ng11) exhibit a coagel to gel transition. The temperature, ¢H, and ¢S of the transitions depend on the length of the aliphatic side chain. The different phase behavior is related to the interplay of the competing molecular interactions that involve the hydrophobic chains of the amphiphiles, their headgroups, and the solvent.¢H, and ¢S of the transitions depend on the length of the aliphatic side chain. The different phase behavior is related to the interplay of the competing molecular interactions that involve the hydrophobic chains of the amphiphiles, their headgroups, and the solvent.