INVESTIGADORES
MARTINELLI Marisa
artículos
Título:
Non-Linear Chemical Dynamics in the Activation of Haloalkanes by Iron (III)
Autor/es:
M MARTINELLI; SANDRA MARTIN; ANGELA R. SUAREZ
Revista:
TETRAHEDRON LETTERS
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Lugar: Amsterdam; Año: 2000
ISSN:
0040-4039
Resumen:
Catalytic dehydrohalogenation of dihaloalkanes with Fe(III) and its mechanism has been investigated.
Damped oscillations of the reaction mixture were observed when the reactions were carried out at 50C in
evacuated systems. We have described the main features of this behavior taking into account the organo-
metallic intermediates, the reversibility of the reaction and the catalyst transformation. # 2000 Published
by Elsevier Science Ltd.
