Influence of anodizing variables on Cr(VI) photocatalytic reduction using TiO2 nanotubes obtained by anodic oxidation

DWOJAK, ANABELA N.; VERA, MARÍA L.; TRAID, HERNÁN D.; MAYDANA, MARÍA F.; LITTER, MARTA I.; SCHVEZOV, CARLOS E.

Environmental Nanotechnology, Monitoring & Management

ELSEVIER SCIENCE SA

Año: 2021 vol. 16

2215-1532

The effect of growth conditions of TiO2 films with nanotubular structures produced by anodic oxidation inelectrolytes containing NH4F in glycerol and water was investigated. The effect of anodizing voltage, time, NH4Fconcentration and initial surface preparation on the formation of nanotube arrays was evaluated. In these cases,the structure was characterized by using scanning electron microscopy, X-ray diffraction and UV?Vis diffusereflectance spectroscopy. The photocatalytic activity was evaluated using hexavalent chromium in the presenceof EDTA (EDTA/Cr(VI) = 1.25 M ratio). The results show that uniform nanotube arrays were only formed with anapplied voltage of 20 V, independently of the value of the other parameters studied. The photocatalytic activityincreases with the NH4F concentration and the anodizing time, due to the increase in the length of the nanotubes,achieving the highest Cr(VI) transformation (93.8%) after 5 h UV irradiation under the optimal conditions.