INVESTIGADORES
LABORDE Miguel Angel
artículos
Título:
Optimized CuO-CeO2 catalysts for COPROX reaction
Autor/es:
F. MARIÑO, G. BARONETTI, M. LABORDE, A. LE VALANT, N. BION, F. EPRON, D. DUPREZ
Revista:
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Lugar: Elsevier; Año: 2008 vol. 33 p. 1345 - 1353
ISSN:
0360-3199
Resumen:
CuO2CeO2 catalyst precursors were synthesized by homogeneous thermal decomposition
of urea. Catalysts containing different Cu/Ce ratios were obtained after calcination of the
precursors at 450 _C and characterized by ICP-OES, N2 adsorption, XRD and TPR. Catalytic
tests were performed in the temperature range 1002300 _C to evaluate the activity of these
samples for the COPROX reaction. A strong synergy between Cu and Ce is evidenced by the
difference in the catalytic activity of the individual oxides (CuO and CeO2), a mechanical
mixture of both oxides and a CuCe mixed catalyst. The synergy between Cu and Ce is
confirmed by the improvement of the reducibility of both cations in the mixed samples.
Nitric acid and ammonium carbonate washed catalysts, especially high-copper-content
samples, are more active than the untreated catalysts suggesting that the washing
procedure could provoke a destruction of the polycrystalline structure that improves the
contact between the reactants and the catalytic sites