INVESTIGADORES
FURLAN Ricardo Luis Eugenio
artículos
Título:
Engineering multilayer chemical networks
Autor/es:
MARTINEZ-AMEZAGA, MAITENA; ORRILLO, ALFREDO GASTON; FURLAN, RICARDO LUIS EUGENIO
Revista:
Chemical Science
Editorial:
Royal Society of Chemistry
Referencias:
Año: 2019 vol. 10
ISSN:
2041-6520
Resumen:
Dynamic multilevel systems emerged in the last few years as new platforms to study thermodynamic systems. In this work, unprecedented fully-communicated three-level systems are studied. First, different conditions were screened to selectively activate thiol/dithioacetal, thiol/thioester, and thiol/disulfide exchanges, individually or in pairs. Some of those conditions were applied, sequentially, to build multilayer dynamic systems wherein information, in the form of relative amounts of building blocks, can be directionally transmitted between different exchange pools. As far as we know, this is the first report of one synthetic dynamic chemical system where relationships between layers can be changed through network operations.
