INVESTIGADORES
FERNANDEZ CIRELLI Alicia
artículos
Título:
The use of aldonolactones for the synthesis of 2-O-mehtyl-L-rhamnose and 2-O-mehtyl-D-mannose
Autor/es:
L. JERONCIC; M. SZNAIDMAN; A. FERNÁNDEZ CIRELLI; R. MUCHNIK DE LEDERKREMER
Revista:
CARBOHYDRATE RESEARCH
Editorial:
Elsevier
Referencias:
Lugar: Amsterdam; Año: 1987 vol. 191 p. 130 - 137
ISSN:
0008-6215
Resumen:
We have previously reported the synthesis of partially substituted aldonolactones by benzoylation of L-rhamnono- and D-mannono-1,4-lactone under controlled conditions. The facile chemoselective reduction of acylated lactones to the lactols suggested their use as intermediates for the synthesis of substituted furanoid sugars, including disaccharides. To test the reactivity of the free hydroxiyl group, we first tried a simple methylation reaction under various conditions.
