High removal of chlorinated solvents by reusable polydimethylsiloxane based absorbents

SALEH MEDINA, LEILA M.; CÁNNEVA, ANTONELA; MOLINARI, FABRICIO N.; D'ACCORSO, NORMA; NEGRI, R. MARTÍN

POLYMER ENGINEERING AND SCIENCE

JOHN WILEY & SONS INC

Año: 2023 vol. 63 p. 366 - 378

0032-3888

The objective of this work is to prepare absorbent materials based on polydimethylsiloxane (PDMS) for the absorption of organic solvents by a relative simple method, with large absorption capacities and reusability. Different particles (ZnO, MgSO4, ZnCl2, and NaHCO3) were first incorporated in PDMS and then removed by immersion in HCl (c) or water. The absorbent materials were characterized by TGA, mercury porosimetry, stress–strain curves, SEM, EDS, XPS, FTIR, and water contact angle. The materials can absorb polar organic chlorinated solvents (carbon tetrachloride, dichloroethene, dichloromethane, and chloroform) more than four times its own weight. Other solvents were also tested showing 2–3 times its own weight. Additionally, these materials show demulsification properties and absorption of oleophilic compounds. The reusability of the material makes them good candidates for remediation of polluted water.