Polybenzimidazole membrane for efficient copper removal from aqueous solutions

COPPOLA, ROXANA E.; LOZANO, HERNÁN E.; CONTIN, MARIO; CANNEVA, ANTONELA; MOLINARI, FABRICIO N.; ABUIN, GRACIELA C.; D'ACCORSO, NORMA B.

POLYMER INTERNATIONAL

JOHN WILEY & SONS LTD

Año: 2022

0959-8103

In this work, thin films of poly(2,5-benzimidazole) (ABPBI) polymer were prepared by the casting method, and sorption studies with aqueous CuSO4 solutions were performed. Surface interaction between Cu (II) and the membrane was studied by spectroscopic analysis (FTIR, Raman and XPS), showing a strong interaction through nitrogen groups of ABPBI and Cu (II). The best conditions for Cu (II) uptake were at pH = 5 and a soaking time of 60 minutes. In these conditions, the sorption isotherm was best fitted by the Langmuir equation and its maximum sorption capacity was estimated to be 1.5 mmol per g. Due to sorption pH dependency, elution studies using hydrochloric acid solution were carried out, showing an almost complete removal of bonded Cu (II) when immersing the ABPBI membrane in the acidic solution. Surface morphology of membranes was studied using SEM-EDS, showing no major changes with sorption and elution experiments. These results show that ABPBI can be considered as an alternative polymer for the development of new materials for the removal of eavy metals.