Atmospheric Chemistry of n-C6F13CH2CHO: Formation from n-C6F13CH2CH2OH, Kinetics,

MALISA S. CHIAPPERO, GUSTAVO A. ARGÜELLO, MICHAEL D. HURLEY, TIMOTHY J. WALLINGTON

JOURNAL OF PHYSICAL CHEMISTRY A

AMER CHEMICAL SOC

Año: 2010 vol. 114 p. 6131 - 6137

1089-5639

Smog chamber FTIR techniques were used to measure k(Cl + n-C6F13CH2CHO) ) (1.84 ( 0.22) × 10-11,k(Cl + n-C6F13CH2CHO) ) (1.84 ( 0.22) × 10-11, k(Cl + n-C6F13CHO) ) (1.75 ( 0.70) × 10-12, and k(OH + n-C6F13CH2CHO) ) (2.15 ( 0.26) × 10-12 cm3(Cl + n-C6F13CHO) ) (1.75 ( 0.70) × 10-12, and k(OH + n-C6F13CH2CHO) ) (2.15 ( 0.26) × 10-12 cm3 molecule-1 s-1 in 700 Torr of N2 or air diluent at 296 ( 2K. The chlorine-atom-initiated oxidation of-1 s-1 in 700 Torr of N2 or air diluent at 296 ( 2K. The chlorine-atom-initiated oxidation of n-C6F13CH2CH2OH in air gives n-C6F13CH2CHO in a molar yield of 99 ( 8%. The atmospheric fate of n-C6F13CH2C(O) radicals is reaction with O2, while the fate of n-C6F13C(O) radicals is decomposition to give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. of n-C6F13CH2C(O) radicals is reaction with O2, while the fate of n-C6F13C(O) radicals is decomposition to give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. of n-C6F13CH2C(O) radicals is reaction with O2, while the fate of n-C6F13C(O) radicals is decomposition to give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. of n-C6F13CH2C(O) radicals is reaction with O2, while the fate of n-C6F13C(O) radicals is decomposition to give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. -C6F13CH2CH2OH in air gives n-C6F13CH2CHO in a molar yield of 99 ( 8%. The atmospheric fate of n-C6F13CH2C(O) radicals is reaction with O2, while the fate of n-C6F13C(O) radicals is decomposition to give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. n-C6F13CH2C(O) radicals is reaction with O2, while the fate of n-C6F13C(O) radicals is decomposition to give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. alcohols and the formation of perfluorocarboxylic acids. n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids.