Direct irradiation of phenol and p-substituted phenols with a laser pulse (266 nm) in homogeneous and micro heterogeneous media. A time-resolved spectroscopy study.

GASTON SIANO; CRESPI, STEFANO; BONESI SERGIO M

JOURNAL OF ORGANIC CHEMISTRY

AMER CHEMICAL SOC

Lugar: Washington; Año: 2020

0022-3263

Direct irradiation of p-substituted phenols under N2 atmosphere in homogeneous (cyclohexane, acetonitrile and methanol) and micellar (SDS) solution was investigated by means of time-resolved spectroscopy. After a laser pulse (266 nm) two transient species were formed, viz. the p-substituted phenol radical-cations and the corresponding phenoxy radicals. The radical-cations showed a broad absorption band located between 390 and 460 nm while the phenoxy radicals showed two characteristic bands centered at 320 nm and 400 ? 410 nm. The deprotonation rate constant of radical-cations (kH) of 105 s-1 and the reaction rate constant of the phenoxy radicals (kR) in the order of 109 ? 1010 M-1.s-1 have been derived. The kH rate constants gave good linear Hammett correlation with positive slope indicating that electron withdrawing substituents enhance the radical-cation acidity. The binding constants (Kb) of the p-substituted phenols with the surfactant were also measured and NOESY experiments showed that phenols were located in the hydrophobic core of the micelle. Finally, computational calculation provided the predicted absorption spectra of the transients and nice linear correlation were obtained between the theoretical and experimental energy of the lower absorption band of these species.