INVESTIGADORES
BERTOLOTTI Sonia Graciela
artículos
Título:
Synthesis and Photoinitiation activity of macroinitiators comprising benzophenone derivatives
Autor/es:
A.M. RUFS, A. VALDEBENITO, M. C. REZENDE, S. BERTOLOTTI, C. PREVITALI, AND M.V. ENCINAS
Revista:
POLYMER
Editorial:
Elsevier
Referencias:
Año: 2008 vol. 49 p. 3671 - 3676
ISSN:
0032-3861
Resumen:
were synthesized in one-step reaction. Triethanolamine was used as coinitiator. These systems were
evaluated as photoinitiators of the N-isopropylacrylamide polymerization in different solvents. They
present a high photoinitiation efficiency that depends on the structure of the initiator and on the medium
properties. In all solvents, the macroinitiators were more efficient than the corresponding lowmolecular-
weight analog. The photophysics of ketones was studied in the different solvents. The triplet
state of the ketone was deactivated by the amine with a diffusional controlled rate. The characterization
of the transients produced in this process explained the influence of the 4-substituent and of the solvent
on the yield of the active radical and the polymerization efficiency.
present a high photoinitiation efficiency that depends on the structure of the initiator and on the medium
properties. In all solvents, the macroinitiators were more efficient than the corresponding lowmolecular-
weight analog. The photophysics of ketones was studied in the different solvents. The triplet
state of the ketone was deactivated by the amine with a diffusional controlled rate. The characterization
of the transients produced in this process explained the influence of the 4-substituent and of the solvent
on the yield of the active radical and the polymerization efficiency.
N-isopropylacrylamide polymerization in different solvents. They
present a high photoinitiation efficiency that depends on the structure of the initiator and on the medium
properties. In all solvents, the macroinitiators were more efficient than the corresponding lowmolecular-
weight analog. The photophysics of ketones was studied in the different solvents. The triplet
state of the ketone was deactivated by the amine with a diffusional controlled rate. The characterization
of the transients produced in this process explained the influence of the 4-substituent and of the solvent
on the yield of the active radical and the polymerization efficiency.