Photoacoustic Calorimetry Study for the Determination of the Partial Volume and Formation Enthalpy of the SO3.- Aqueous Radical

S.G. BERTOLOTTI, M. A. BRUSA, M. A. GRELA,AND M. S. CHURIO

CHEMICAL PHYSICS LETTERS

Elsevier

Año: 2008 vol. 80 p. 206 - 211

0009-2614

Photoacoustic calorimetry was applied to the photolysis at 266 nm of aqueous peroxodisulfate ion in the presence of bisulfite. A time-resolved analysis of the signals at variable temperature (282–295 K) yields the heat of formation (530 kJ mol1) and the partial molal volume (50 mL mol1) of aqueous sulfite radical. The ca. 11 mL mol1 difference between the experimental molal volumes of SO 3 and the parent closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. The ca. 11 mL mol1 difference between the experimental molal volumes of SO 3 and the parent closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. The ca. 11 mL mol1 difference between the experimental molal volumes of SO 3 and the parent closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. The ca. 11 mL mol1 difference between the experimental molal volumes of SO 3 and the parent closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. The ca. 11 mL mol1 difference between the experimental molal volumes of SO 3 and the parent closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. The ca. 11 mL mol1 difference between the experimental molal volumes of SO 3 and the parent closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. closed shell ion with similar intrinsic size SO3H, indicates a diverse rearrangement of the solvent molecules around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electronic distribution. around each species, probably as a result of the dissimilar electro