INVESTIGADORES
BEN ALTABEF Aida
artículos
Título:
Synthesis and characterization of 2-chloroethyl (methylsulfonyl) methanesulfonate
Autor/es:
A. BEN ALTABEF; JORGE E. GALVÁN; M. ELIANA DEFONSI; M. E. TUTTOLOMONDO; G. A. ECHEVERRIA; O. PIRO; M. ARENA ; R. MOLINA; SONIA E. ULIC
Revista:
NEW JOURNAL OF CHEMISTRY
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Lugar: CAMBRIDGE; Año: 2018
ISSN:
1144-0546
Resumen:
The aim of this work is to evaluate the structural,vibrational properties and the biological activity of 2-Chloroethyl(methylsulfonyl) methanesulfonate, CH3SO2CH2SO2OCH2CH2Cl(Clomesone). The solid state molecular structure has been isolated andcharacterized by experimental (X-ray diffraction) and theoretical (DFT method)methodologies. The molecules are packed through C?H···O bifurcated interactionsand Cl···Cl interactions. The experimental investigations were supplemented byquantum chemical calculation and Hirshfeld surface calculations. Furthermore,the infrared and Raman spectra for the solid phase have been recorded and theobserved bands assigned to the vibrational normal modes. The study wascompleted by The Atoms-in-Molecules (AIM) theory and natural bond orbital (NBO)analysis. Finally, we study the function of Clomesone on biofilm formation andthe study on a methansulfonate complex with respect to QS activity.
