“Layered crystal structure and vibrational spectra of Sodium trichloromethanesulfonate. An experimental and theoretical study”

M. E. TUTTOLOMONDO; O. E. PIRO; E. L. VARETTI; A. BEN ALTABEF

ZAAC

Wiley InterScience

Año: 2006 vol. 632 p. 1501 - 1507

1521-3749

Abstract. The NaCCl3SO3.H2O salt was studied by X-ray diffraction methods, which show that it crystallizes in the monoclinic P21/c methods, which show that it crystallizes in the monoclinic P21/c methods, which show that it crystallizes in the monoclinic P21/c methods, which show that it crystallizes in the monoclinic P21/c methods, which show that it crystallizes in the monoclinic P21/c The NaCCl3SO3.H2O salt was studied by X-ray diffraction methods, which show that it crystallizes in the monoclinic P21/cP21/c space group, with a
12.558(5), b
5.814(3), c
10.679(5)A ° ,a
12.558(5), b
5.814(3), c
10.679(5)A ° , β
103.76(3)°, and Z
4. The solid is arranged into neutral slabs, parallel to each other and to the crystal bc plane, being each slab held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported parallel to each other and to the crystal bc plane, being each slab held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported parallel to each other and to the crystal bc plane, being each slab held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported parallel to each other and to the crystal bc plane, being each slab held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported parallel to each other and to the crystal bc plane, being each slab held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported
103.76(3)°, and Z
4. The solid is arranged into neutral slabs, parallel to each other and to the crystal bc plane, being each slab held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported bc plane, being each slab held mainly by ionic forces. An infrared and Raman study of that compound was also performed and an assignment of the observed spectral features was made, correcting results previously reported Introduction Several compounds having the CF3SO2 moiety were studied in our laboratory using vibrational spectroscopic techni ques [1, 2]. Such studies included the ammonium trifluoromethanesulfonate salt, NH4CF3SO3 [3], for which the polarized infrared and Raman spectra were obtained and used to ensure the band assignments. The chlorinated anion is now considered in the form of the NaCCl3SO3·H2O salt. No structural data is known for the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and infrared and Raman spectra were obtained and used to ensure the band assignments. The chlorinated anion is now considered in the form of the NaCCl3SO3·H2O salt. No structural data is known for the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and infrared and Raman spectra were obtained and used to ensure the band assignments. The chlorinated anion is now considered in the form of the NaCCl3SO3·H2O salt. No structural data is known for the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and infrared and Raman spectra were obtained and used to ensure the band assignments. The chlorinated anion is now considered in the form of the NaCCl3SO3·H2O salt. No structural data is known for the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and studied previously by Miles et al. [4], Bürger et al. [5] and infrared and Raman spectra were obtained and used to ensure the band assignments. The chlorinated anion is now considered in the form of the NaCCl3SO3·H2O salt. No structural data is known for the studied substance, a fact which prompted us to undertake a X-ray diffraction study. The vibrational properties of the [CCl3SO3] anion were studied previously by Miles et al. [4], Bürger et al. [5] and