INVESTIGADORES
ALVAREZ Vera Alejandra
artículos
Título:
Compatibilization and Properties of EVA Copolymers Containing Surface-Functionalized Cellulose Microfibers
Autor/es:
MARIANO PRACELLA; M. MINHAZ-UL HAQUE; VERA ALVAREZ
Revista:
MACROMOLECULAR MATERIALS AND ENGINEERING (PRINT)
Editorial:
WILEY-V C H VERLAG GMBH
Referencias:
Año: 2010 vol. 295 p. 949 - 957
ISSN:
1438-7492
Resumen:
Cellulose microfibers were modified with two different bi-functional monomers. Composites of EVA copolymer with modified and unmodified cellulose were prepared by melt mixing. The samples were analyzed by SEM, XRD, FT-IR, DSC, TGA, DMTA and tensile mechanical tests. SEM showed that the presence of reactive groups on cellulose surface enhanced the compatibility,improving the fiber/matrix interfacial adhesion.FT-IR disclosed the occurrence of chemical reactions between the functionalized cellulose and polymer chains. The incorporation of fibers affected the
crystallization behaviour and crystallinity of the polymer matrix. Composites with GMA modified cellulose displayed better compatibility, higher thermal and mechanical properties.
