INQUISAL   20936
INSTITUTO DE QUIMICA DE SAN LUIS "DR. ROBERTO ANTONIO OLSINA"
Unidad Ejecutora - UE
artículos
Título:
Multivariate factorial analysis to design a robust batch leaching test to assess the volcanic ash geochemical hazard. Journal of Hazardous Materials.
Autor/es:
RUGGIERI FLAVIA; GIL, RAÚL; JOSE LUIS FERNANDEZ TURIEL; JULIO SAAVEDRA; DOMINGO GIMENO; AGUSTIN LOBO; LUIS D. MARTINEZ; ALEJANDRO RODRIGUEZ GONZALAEZ
Revista:
JOURNAL OF HAZARDOUS MATERIALS.
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Lugar: Amsterdam; Año: 2012 vol. 213 p. 273 - 284
ISSN:
0304-3894
Resumen:
A method to obtain robust information on short term leaching behaviour of volcanic ashes has been developed independently on the sample age. A mixed factorial design (MFD) was employed as a multivariate strategy for the evaluation of the effects of selected control factors and their interactions (amount of sample (A), contact time (B), and liquid to solid ratio or L/S (C)) on the leaching process of selected metals (Na, K, Mg, Ca, Si, Al, V, Mn, Fe, and Co) and anions (Cl− and SO42−). Box plots of the data acquired were used to evaluate the reproducibility achieved at different experimental conditions. Both the amount of sample (A) and leaching time (B) had a significant effect on the element stripping whereas the L/S ratio influenced only few elements. The lowest dispersion values have been observed when 1.0 g was leached with an L/S ratio equal to 10, shaking during 4 h. The entire method is completed within few hours, and it is simple, feasible and reliable in laboratory conditions.