Determination of Zn(II) in natural waters by ICP-OES with on-line preconcentration using a simple solid phase extraction system

LUIS A. ESCUDEROA; LUIS D. MARTINEZ; JOSÉ A. SALONIA; JOSÉ A. GASQUEZ

MICROCHEMICAL JOURNAL

ELSEVIER SCIENCE BV

Año: 2010 vol. 95 p. 64 - 68

0026-265X

Abstract An on-line zinc preconcentration and determination system implemented with inductively coupled plasma optical emission spectrometry (ICP-OES) was developed. The zinc was precipitated and retained on a minicolumn filled with ethyl vinyl acetate (EVA) at pH 9.0, without using any complexing reagent. The zinc ions were eluted from the minicolumn with 10% (v/v) hydrochloric acid. Experimental conditions including pH and sample loading and eluting variables were evaluated and established. An enrichment factor (EF) of 44 was obtained for Zn2+ with a preconcentration time of 120 s. Under the optimal conditions, the value of the limit of detection (3σ) for the preconcentration of 10 mL of sample was 0.08 μg L− 1. The sampling frequency was about 24 h− 1. The precision for six replicate determinations (repeatability conditions) at 50 μg L− 1 Zn level was 3.94% relative deviation standard (RSD), calculated from the peak heights obtained. The methodology was successfully applied to the determination of zinc in tap water samples and in a certified VKI reference material QC Metal LL1 DHI (Water & Environment) Denmark.